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AS & A Level Chemistry 9701 · Chemical bonding · 3.5

Shapes of molecules: past paper questions

125 real questionsasked in 9 of the last 10 exam series2019–2026usually: Complete, Identify, Explain, Draw, Describe

Real questions on shapes of molecules

The newest 20 of 125 written questions. Open one to see it on the real paper.

  1. 9701/41 · May/June 2026 · Q6b(ii)[2]

    This complex shows stereoisomerism. Draw three-dimensional diagrams to show all the stereoisomers of this complex. The C 2 O 42– ion can be represented using O O .

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  2. 9701/41 · May/June 2026 · Q6b(iii)[1]

    State the type or types of stereoisomerism shown by this complex.

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  3. 9701/41 · May/June 2026 · Q8b(i)[2]

    Complete Table 8.1 to identify the splitting patterns for proton environments r, s, t and u. Table 8.1 proton environment name of splitting pattern r s t u

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  4. 9701/41 · May/June 2026 · Q8b(ii)[2]

    The proton ( 1 H) NMR spectrum of M dissolved in CDCl 3 is obtained. State and explain how this spectrum differs from the proton ( 1 H) NMR spectrum of M dissolved in D 2 O.

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  5. 9701/41 · October/November 2025 · Q5e[2]

    The complex ion [Au(CN) 2 Br 2 ] – displays geometrical (cis / trans) isomerism. Draw the structure of trans-[Au(CN) 2 Br 2 ] – . State its shape and the Br-Au-Br bond angle.

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  6. 9701/42 · October/November 2025 · Q2a(i)[1]

    Use two words to complete the sentence. This reaction involves of the single

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  7. 9701/42 · October/November 2025 · Q2a(iii)[1]

    Use VSEPR theory to predict the bond angle at the nitrogen atom in an HNO 2 molecule. bond angle =

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  8. 9701/42 · October/November 2025 · Q6a(ii)[2]

    Give the formula and charge of the octahedral complex formed by Ni 2+ ions with ethanedioate ions. This is complex F. F =

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  9. 9701/42 · October/November 2025 · Q6a(iii)[1]

    Identify which complex, E or F, exists as a mixture of two stereoisomers and the type of stereoisomerism involved. The complex which exists as a mixture of two stereoisomers is .

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  10. 9701/43 · October/November 2025 · Q5e[2]

    The complex ion [Au(CN) 2 Br 2 ] – displays geometrical (cis / trans) isomerism. Draw the structure of trans-[Au(CN) 2 Br 2 ] – . State its shape and the Br-Au-Br bond angle.

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  11. 9701/23 · May/June 2025 · Q4b(i)[2]

    Use Fig. 4.2 to predict the shape and bond angle of a molecule of SO 2 . shape

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  12. 9701/42 · May/June 2025 · Q7a[1]

    2-aminobutane, CH 3 CH(NH 2 )CH 2 CH 3 , exists as a mixture of two enantiomers. Define enantiomers.

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  13. 9701/22 · February/March 2025 · Q1b(ii)[1]

    Predict the shape of a molecule of PCl 5 . (ii)

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  14. 9701/22 · February/March 2025 · Q4b(iii)[1]

    N has a chiral centre. Explain what is meant by a chiral centre. Important values, constants and standards molar gas constant R = 8.31 J K –1 mol –1 Faraday constant F = 9.65 × 10 4 C mol –1 Avogadro constant L = 6.02 × 10 23 mol –1 electronic charge e = –1.60 × 10 –19 C molar volume of gas V m = 22.4 dm 3 mol –1 at s....

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  15. 9701/21 · October/November 2024 · Q3d(ii)[1]

    Deduce the shape of a molecule of SiH 4 .

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  16. 9701/22 · October/November 2024 · Q3b(iv)[1]

    Suggest the shape of the [Al(OH) 4 ] – ion.

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  17. 9701/22 · October/November 2024 · Q4d(i)[1]

    Identify the type of isomerism shown by E and 1,2-dibromoethane.

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  18. 9701/23 · October/November 2024 · Q3d(ii)[1]

    Deduce the shape of a molecule of SiH 4 .

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  19. 9701/41 · October/November 2024 · Q5a[2]

    Label one bond angle on each of complexes P, Q, R and S, and identify the size of the angle in degrees.

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  20. 9701/41 · October/November 2024 · Q5b[2]

    Identify the shapes of complexes P, Q, R and S. P R Q

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What examiners said

There were many good answers here although many incorrect answers were also provided. Many candidates omitted the bi– prefix from bipyramidal.

— Examiner report, February/March 2025, 9701/22 Q1(b)(ii) (Cambridge)

This was often well answered. The phrase ‘surrounded by’ is not a legitimate substitute for ‘attached to’ or ‘bonded to’. Some candidates described the substituents on a chiral carbon as molecules or compounds: this this was not credited.

— Examiner report, February/March 2025, 9701/22 Q4(b)(iii) (Cambridge)

A high proportion of candidates correctly identified the number of primary, secondary and tertiary alcohol groups, in glucose, as 1, 4 and zero, respectively.

— Examiner report, October/November 2023, 9701/21 Q3(e)(i) (Cambridge)

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Shapes of molecules — AS & A Level Chemistry 9701 past paper questions | AssessPro