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AS & A Level Chemistry 9701 · Reaction kinetics · 8.3

Homogeneous and heterogeneous catalysts: past paper questions

60 real questionsasked in 7 of the last 10 exam series2019–2025usually: Suggest, Explain, Describe, State, Identify

Real questions on homogeneous and heterogeneous catalysts

The newest 20 of 60 written questions. Open one to see it on the real paper.

  1. 9701/21 · October/November 2025 · Q4a(ii)[2]

    Suggest a suitable reagent for reaction 2.

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  2. 9701/21 · October/November 2025 · Q4a(iv)[1]

    C 2 H 5 CH 2 OH can be directly converted to C 3 H 6 . Suggest the reagent and conditions for this conversion.

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  3. 9701/23 · October/November 2025 · Q3c(i)[1]

    The reaction is initiated by the bond fission of Cl 2 . State the type of bond fission shown in the initiation step.

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  4. 9701/23 · October/November 2025 · Q3c(ii)[2]

    Complete the equations to show the two propagation steps that follow the initiation step. propagation 1 C 5 H 10 + C 5 H 9 • +

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  5. 9701/23 · October/November 2025 · Q3c(iii)[1]

    The final step is shown. C 5 H 9 • + Cl • C 5 H 9 Cl Give the name for this step in the reaction.

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  6. 9701/41 · October/November 2025 · Q3a[1]

    Solid manganese( IV ) oxide, MnO 2 , catalyses the decomposition of hydrogen peroxide. 2H 2 O 2 (aq) 2H 2 O(l) + O 2 (g) State the type of catalysis for this reaction. Explain your answer.

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  7. 9701/42 · October/November 2025 · Q2e[2]

    NO 2 is present in the exhaust gases of cars. It can react with carbon monoxide, CO, on the surface of a heterogeneous catalyst in the car’s catalytic converter. Describe the mode of action of this heterogeneous catalyst.

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  8. 9701/21 · May/June 2025 · Q3a(iii)[1]

    State the role of nickel when it is added to reaction 1. (iii)

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  9. 9701/21 · May/June 2025 · Q3a(iv)[1]

    Annotate Fig. 3.2 to show the effect of adding nickel to reaction 1 at temperature T. number of molecules E A energy

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  10. 9701/43 · May/June 2025 · Q2c[3]

    Sulfur dioxide, SO 2 , reacts very slowly with oxygen in the atmosphere, forming sulfur trioxide, SO 3 . This reaction is much faster in the presence of NO. Explain the role of NO in this process. Include chemical equations in your answer.

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  11. 9701/42 · February/March 2025 · Q6b(i)[1]

    Suggest the type of reaction that occurs in step 1.

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  12. 9701/41 · October/November 2024 · Q3b(i)[1]

    Identify two metals that act as heterogeneous catalysts in the removal of NO 2 from the exhaust gases of car engines. and

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  13. 9701/42 · October/November 2024 · Q1b(ii)[1]

    Name the metal catalyst in the Haber process and explain why it is a heterogeneous catalyst. metal

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  14. 9701/42 · October/November 2024 · Q1b(iii)[2]

    Platinum acts as a heterogeneous catalyst in the removal of nitrogen dioxide, NO 2 , from the exhaust gases of car engines. Describe the mode of action of a platinum catalyst in this process.

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  15. 9701/42 · October/November 2024 · Q1b(iv)[1]

    NO 2 acts as a homogeneous catalyst in the oxidation of atmospheric sulfur dioxide, SO 2 . Write equations for the two reactions that occur. equation

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  16. 9701/43 · October/November 2024 · Q3b(i)[1]

    Identify two metals that act as heterogeneous catalysts in the removal of NO 2 from the exhaust gases of car engines. and

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  17. 9701/43 · October/November 2024 · Q3b(ii)[2]

    Iron acts as a heterogeneous catalyst in the Haber process. Describe the mode of action of this iron catalyst.

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  18. 9701/43 · October/November 2024 · Q3b(iv)[1]

    Explain the difference between a homogeneous catalyst and a heterogeneous catalyst.

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  19. 9701/42 · February/March 2024 · Q6b(i)[1]

    State the essential conditions for reaction 1.

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  20. 9701/43 · October/November 2023 · Q3d[1]

    The decomposition of H 2 O 2 (aq) is catalysed by aqueous iron(III) chloride and by silver metal. Identify which of these two catalysts is acting as a homogeneous catalyst. Explain your answer. homogeneous catalyst explanation

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What examiners said

Most candidates correctly identified the catalyst as FeCl3 stating it was in the same phase as H2O2.

— Examiner report, October/November 2023, 9701/43 Q3(d) (Cambridge)

It was generally well known how a catalyst affects a reaction. Some ambiguity was seen in answers that described the effect of catalysts as increasing the number of collisions between particles rather than increasing the frequency of successful collisions.

— Examiner report, May/June 2023, 9701/22 Q4(c)(iv) (Cambridge)

Stronger candidates clearly described the regeneration of the catalyst. Some candidates were vague and imprecise, for example ‘the catalyst did not change in the reaction’.

— Examiner report, May/June 2023, 9701/22 Q4(c)(v) (Cambridge)

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Homogeneous and heterogeneous catalysts — AS & A Level Chemistry 9701 past paper questions | AssessPro